Preparation and optical properties of Cds/Epoxy nanocomposites

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Main Authors: Kasim, F. A., Mahdi, M. A., Hassan, J. J., Al-Ani, S. K. J., Kasim, S. J.
Other Authors: salwan_kamal@yahoo.com
Format: Article
Language:English
Published: Universiti Malaysia Perlis 2016
Subjects:
Cds
XRD
Online Access:http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41263
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spelling my.unimap-412632017-11-21T03:24:46Z Preparation and optical properties of Cds/Epoxy nanocomposites Kasim, F. A. Mahdi, M. A. Hassan, J. J. Al-Ani, S. K. J. Kasim, S. J. salwan_kamal@yahoo.com Cds Epoxy Nanocomposites XRD Link to publisher's homepage at http://ijneam.unimap.edu.my/ The Cds/Epoxy nanocomposites (5%,205 Cds ratio) were prepared by in situ method usnig cadmium acetate and thiourea as a source of Cd2+ and S2- ions to form Cds nanoparticles in epoxy matrix solution. The X-ray diffraction patterns show that crystallinity of the samples was decreased with increase in the Cds ratio in the nanocomposites. The FTIR and the UV-Visible absorption spectra were performed for prepared samples to determine the assignment bands and the absorption edges respectively. The effective mass model has been used to calculate the diameters of the Cds nanoparticles and they were 4.5 and 4.6 nm for 5% and 20% Cds+ Epoxy respectively. The photoluminescence spectra of Cds/Epoxy showed two emission peaks, the first one varies form 470 to 480 nm for 5% and 20% Cds+ Epoxy respectively, due to energy gap variation with particle size, and the second one at 600 nm bears the signature of the red emission (Lambe_Klick model) which could be due to the recombination of electrons trapped at sulfur (S) vacancies with valence-band-free holes. 2016-04-08T07:25:57Z 2016-04-08T07:25:57Z 2012 Article International Journal of Nanoelectronics and Materials, vol.5 (1), 2012, pages 57-66 1985-5761 (Printed) 1997-4434 (Online) http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41263 en Universiti Malaysia Perlis
institution Universiti Malaysia Perlis
building UniMAP Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaysia Perlis
content_source UniMAP Library Digital Repository
url_provider http://dspace.unimap.edu.my/
language English
topic Cds
Epoxy
Nanocomposites
XRD
spellingShingle Cds
Epoxy
Nanocomposites
XRD
Kasim, F. A.
Mahdi, M. A.
Hassan, J. J.
Al-Ani, S. K. J.
Kasim, S. J.
Preparation and optical properties of Cds/Epoxy nanocomposites
description Link to publisher's homepage at http://ijneam.unimap.edu.my/
author2 salwan_kamal@yahoo.com
author_facet salwan_kamal@yahoo.com
Kasim, F. A.
Mahdi, M. A.
Hassan, J. J.
Al-Ani, S. K. J.
Kasim, S. J.
format Article
author Kasim, F. A.
Mahdi, M. A.
Hassan, J. J.
Al-Ani, S. K. J.
Kasim, S. J.
author_sort Kasim, F. A.
title Preparation and optical properties of Cds/Epoxy nanocomposites
title_short Preparation and optical properties of Cds/Epoxy nanocomposites
title_full Preparation and optical properties of Cds/Epoxy nanocomposites
title_fullStr Preparation and optical properties of Cds/Epoxy nanocomposites
title_full_unstemmed Preparation and optical properties of Cds/Epoxy nanocomposites
title_sort preparation and optical properties of cds/epoxy nanocomposites
publisher Universiti Malaysia Perlis
publishDate 2016
url http://dspace.unimap.edu.my:80/xmlui/handle/123456789/41263
_version_ 1643802788578197504
score 13.154949